Salt Analysis Experiment Class 12

Important very easy Salt Analysis Experiment Class 12 written by Honorable Professor Sehar Mubeen. These experiments are very helpful in the preparation of the Salt Analysis Experiment Class 12 in Chemistry for the students and this is according to the Institute.

Summary and Contents:                                      
Topics which are discussed in the notes are given below:
  • Important Salt Analysis Experiment for intermediate part - II students.
  • Acid Radicals,  Basic Radicals
  • Preparation of original solution for basic Radicals
  • Important class 12 chemistry practical salt analysis for intermediate part - II students.
  • Preliminary Examination of the salt
  • Dry Test
  • Important 12th chemistry salt analysis pdf for intermediate part - II students.
  • All Experiments of the Salt Analysis in Chemistry.
  • QUALITATIVESALT ANALYSISIt is the analysis which involves the detection, identification and confirmation of the radicals present in a salt.
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  • SALT:  It is an ionic compound which is formed by the neutralization (other than water) of an acid with a base. 
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  • Base NaOH +  Acid HCI → Salt NaCl + Water H2O. A salt is made up of two parts.
  • (i) Acid Radical:  The part of a salt which comes from an acid during neutralization is called acid radical. Acid radicals bear negative charge e.g., CO2- 3, CI1-, CH3, COO1-, SO2- 4. ( H is also an acid radical but it bears positive charge)
  • Important chemistry practical class 12 salt analysis for intermediate part - II students.
  • (ii) Basic Radical: The part of a salt bearing positive charge and which comes from a base during neutralization is called a basic radical. Basic radicals are usually metal cations. e.g., Ca2+, Na+, K+, Al3+ ( NH4+, is a basic radical but it is not a metal cation ).
  • Important chemistry salt analysis class 12 for intermediate part - II students.
  • DRYTEST: The test which is directly performed with a dry salt without making its solution is called a dry test. e.g., Flame test, Borax bead test, Filter ash test etc.
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  • WETTEST: A test, performed with the solution of a salt is called we test. e.g., Ring test, Lake test, Layer test etc. For salt analysis, radicals are divided into six basic groups and three acidic groups. 
  • Important salt analysis class 12 practical for intermediate part - II students.
  • BASIC RADICALS: Group-1: Silver  (Ag1+ ), Plumbous ( Pb2+ ), Mercurous ( Hg2+ ).
  • Group-II: Cupric ( Cu2+ ), Cadmium (Cd2+), Lead  (Pb2+), Mercuric (Hg2+), Bismith (Bi3+ ), Arsenic ( As3+ ), Antimony ( Sb3+ ), Tin ( Sn2+ ).
  • Important salt analysis class 12 practical pdf for intermediate part - II students.
  • Group-III: Aminium ( Al3+ ), Ferrous ( Fe2+ ), Ferric ( Fe3+ ), Chromium ( Cr3+ ).
  • Important lead chloride salt analysis class 12 for intermediate part - II students.
  • Group-IV: Nickel ( Ni2+ ), Cobalt ( Co2+ ), Zinc ( Zn2+ ), Manganese ( Mn2+ ).
  • Important aluminium sulphate salt analysis class 12 for intermediate part - II students.
  • Group-V: Barium ( Ba2+ ), Strontium ( Sr2+ ), Calcium ( Ca2+ ).
  • Important lead nitrate salt analysis class 12 for intermediate part - II students.
  • Group-VI: Magnesium ( Mg2+ ), Sodium ( Na+ ), Potasium ( K+ ), Ammonium (NH4+).
  • Important ammonium acetate salt analysis class 12 for intermediate part - II students.
  • TOTAL NUMBER OF BASIC RADICALS: Group - l =  3 radicals, Group - ll =  8 radicals, Group - lll =  3 radicals, Group - lv =  4 radicals, Group - lv =  3 radicals, Group - vl =  4 radicals, Total  =  25 radicals
  • Important ammonium carbonate salt analysis class 12 for intermediate part - II students.
  • ACID RADICALS(i) Dilute Acid Group: Carbonate ( CO3 2- ), Bicarbonate ( HCO3 1- ), Nitrite ( NO3 1- ), Sulphide (S2-), Sulphite (SO3 2-), Thiosulphate S2 O3 2-
  • Important ammonium chloride salt analysis class 12 for intermediate part - II students.
  • (ii) Concentrated H2SO4 Group: Chloride ( Cl- ), Bromide ( Br- ), Iodide ( I- ), Nitrate (NO3 1-, Acetate ( CH3COO1- ), Oxalate ( C2O4 2- )
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  • (iii) Special Group: Sulphate ( SO4 2- ), Phosphate ( PO4 3- )
  • Important lead acetate salt analysis practical class 12 for intermediate part - II students.
  • TOTAL NUMBER OF ACID Dilute acid group = 6 radicals,  Concentrated H2SO4 group = 6 radicals, Special group = 2 radicals.   Total = 14 radicals
  • Important ammonium chloride salt analysis practical class 12 for intermediate part - II students.
  • Acid Radicals: All acid radicals are detected by dry tests except sulphate ( SO4 2- ) and phosphate ( PO4 3- ) of special group.
  • Important ammonium oxalate salt analysis class 12 for intermediate part - II students.
  • Detection of Radicals of Dilute Acid Group: Radicals of dilute acid group are detected by treating the salt with dilute H2SO4 or dil. HCI.
  • Important ammonium sulphate salt analysis class 12 for intermediate part - II students.
  • Detection of Radicals of Concentrated H2SO4 Group: Radicals of concentrated H2SO4 group are detected by treating the salt with concentrated H2SO4 and heat.
  • Important barium chloride salt analysis class 12 for intermediate part - II students.
  • Detection of Special Group Radicals: Radicals of special group cannot be detected by dry tests. BaCl2 + Conc. HCl solution is used to detect and differentiate between SO4 2- and PO4 3- .
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  • (1) Dilute Acid: CO3 2-, HCO3 1-, NO2 1-, S2-, SO3 2-, S2O3 2-
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  • (2) Cone H2SO4 Group: Cl1-, Br1-, l1-, NO3 1-, CH3COO1-, C2O4 2-
  • Important calcium carbonate salt analysis class 12 for intermediate part - II students.
  • (3) Special Group: SO4 2- , PO4 3- 
  • Important lead acetate salt analysis class 12 for intermediate part - II students.

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